A six-lump kinetic model for HDPE/VGO blend hydrocracking

نویسندگان

چکیده

A six lump-based kinetic model has been developed for the hydrocracking of high-density polyethylene (HDPE) blended with vacuum gas oil (VGO) over a PtPd/HY zeolite catalyst. The blend (20 wt% HDPE and 80 VGO) hydrocracked in semi-continuous stirred tank reactor under following conditions: 400–440 °C; H2 bar; catalyst to feed (C/F) weight ratio, 0.05–0.1 gcat gfeed−1; reaction time, 15–120 min; stirring rate, 1300 rpm. model, which is an approach tackle complex mechanism behind HDPE/VGO blend, predicts evolution time product distribution (gas, naphtha, light cycle (LCO), heavy (HCO), coke). its computed parameters have used simulation establishing that C/F ratio 0.075 gfeed−1 temperature–time combinations 430 °C–10 min 440 °C–70 are optimal operating conditions. Under these conditions, proper balance between HCO conversion (>80 %), (>60 %) liquid fuel production index (>1.0) would be obtained. This could serve as basis scaling-up valorization waste plastics by co-feeding them industrial units, within Waste-Refinery strategy.

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ژورنال

عنوان ژورنال: Fuel

سال: 2023

ISSN: ['0016-2361', '1873-7153']

DOI: https://doi.org/10.1016/j.fuel.2022.126211